摘要
众所周知的是金属铑与手性双烯配体组成的催化体系在不对称芳基反应中有着优秀的表现。手性配体的合成与设计的不对称催化领域的重点也是难点。本文重点介绍了手性双烯参与的不对称芳基化反应的最新进展,合成了一系列手性双烯配体,以及其在不对称芳基化/环化反应中的应用。
关键词:手性二烯配体;不对称催化反应;环化反应
ABSTRACT
It is well known that the catalytic system composed of metallic rhodium and a chiral diene ligand has excellent performance in asymmetric aryl reactions. The synthesis and design of chiral ligands is the key point in the field of asymmetric catalysis. This article focuses on the recent progress of asymmetric arylation reactions involving chiral diene, a series of chiral diene ligands have been synthesized, and their applications in asymmetric arylation / cyclization reactions.
Key words: Chiral diene ligands; asymmetric catalytic reactions; cyclization reactions
目录
摘要 1
ABSTRACT 2
背景介绍 4
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